Abstract
In the title compound, [Pt(C11H8N)Cl(C2H6OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt—S = 2.2181 (11) Å] and the chlorido ligand is trans to the carbon donor of 2-(2-pyridyl)phenyl [Pt—Cl = 2.4202 (10) Å]. The [2-(2-pyridyl)phenyl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent interplanar separations of 3.44 (9) and 3.50 (2) Å.
Highlights
The [2(2-pyridyl)phenyl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent interplanar separations of 3.44 (9) and 3.50 (2) A
This work was in part supported by a Grant-in-Aid for Scientific Research (A) (No 17205008), a Grant-in-Aid for Specially Promoted Research (No 18002016), and a Grant-inAid for the Global COE Program (‘Science for Future Molecular Systems’) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: AT2633)
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.007 A; R factor = 0.024; wR factor = 0.064; data-to-parameter ratio = 17.3. In the title compound, [Pt(C11H8N)Cl(C2H6OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt—S = 2.2181 (11) A ] and the chlorido ligand is trans to the carbon donor of 2-(2-pyridyl)phenyl [Pt—Cl = 2.4202 (10) A ]. The [2(2-pyridyl)phenyl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent interplanar separations of 3.44 (9) and 3.50 (2) A. Crystal data [Pt(C11H8N)Cl(C2H6OS)] Mr = 462.85 Monoclinic, C2=c a = 22.414 (3) Ab = 10.0205 (16) Ac = 14.057 (2) A = 124.512 (2).
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