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Abstract
The title compound, [ZnCl2(C13H11N3)]·C3H7NO, crystallized in the monoclinic crystal system in space group P21/n. The asymmetric unit contains one neutral complex mol-ecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with di-methyl-formamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24 (8)°. The Zn(II) ion shows distorted tetra-hedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N-H⋯O, N-H⋯Cl, C-H⋯Cl hydrogen bonding.
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Schedule a callMore From: Acta crystallographica. Section E, Crystallographic communications
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