Chitosan-grafted nonwoven geotextile for heavy metals sorption in sediments

Abstract

Functionalized polypropylene nonwoven (PP) geotextiles can be used as a new eco-friendly way to trap heavy metals in sediments. Chitosan was chosen as sorbent because of its ability to trap heavy metals, its natural origin (from shells) and its low cost. PP was first functionalized with acrylic acid using a low pressure cold plasma process, in order to bring reactive carboxylic functions onto the surface. Chitosan was then covalently grafted on the acrylic acid modified PP. The functionalized surfaces were characterized by Fourier Transform Infrared Spectroscopy–Attenuated Total Reflectance (FTIR–ATR) and X-ray Photoelectron Spectroscopy (XPS) and evidence of chitosan grafting was given. The ability of the functionalized geotextile to trap heavy metals was then investigated. Copper was chosen as a model heavy metal, and artificial solutions of CuSO4 were prepared for the experiments. Sorption studies were carried out at 20°C with Polypropylene-grafted-Acrylic acid-Chitosan (PP-g-AA-chitosan) varying the concentration of copper in polluted solutions to evaluate the maximum of adsorption of the surface: the textile can chelate copper increasingly as a function of the initial copper concentration until 830ppm. At this concentration, it reaches a plateau at about 30mg of trapped copper per gram of geotextile. The effects of pH and of the ionic strength (adsorption in a NaCl containing solution) were finally investigated. The trapping of Cu2+ decreases slowly when the ionic strength increases. When there are 30g/L NaCl in the artificial polluted solution (like in seawater), only 20mg of Cu2+ can be trapped per g of geotextile. Finally, the optimum pH to trap the maximum amount of copper was determined to be 4.8, which corresponds to the optimum pH for the chitosan solubility.