Chitosan-based sorbent for efficient removal and extraction of ciprofloxacin and norfloxacin from aqueous solutions.

Abstract

Nanosheets prepared from magnesium oxide, chitosan and graphene oxide (MgO/Chit/GO) were hydrothermally synthesized and used as a sorbent for removal of ciprofloxacin and norfloxacin from aqueous solutions. Residual antibiotics in sample were determined by HPLC/UV instrument. The sorbent was characterized by FTIR, XRD, BET, SEM, and TEM. Its high adsorption capacity is attributed to the high surface area (294m2.g-1) as compared to bare MgO/chit or bare GO. The pore size of the mesoporous sorbent typically is 15Å. The adsorption isotherms for the two model antibiotics studied (norfloxacin, ciprofloxacin) can be described with the Langmuir model, and the maximum adsorption capacities are 1111 and 1000mg.g-1 for ciprofloxacin and norfloxacin, respectively. The analysis of the kinetic data revealed that the synthesized sorbent followed pseudo-second-order kinetics and the maximum equilibrium was at over 120 and 150min for ciprofloxacin and norfloxacin, respectively. Therefore, it is introduced as an economical, eco- friendly, and high-performance sorbent for removal of antibiotics from aqueous solutions. Graphical abstract Schematic presentation of dispersion of magnesium oxide/chitosan/graphene oxide (MgO/chit/GO) nanosheets in waste water for removal of ciprofloxacin and norfloxacin as water pollutants.