Abstract
AbstractInspired by the photosynthesis and protein structure of green plants in nature, TCPP‐(FF)4, a porphyrin‐dipeptide derivative with chiral and optical properties, was synthesized by chemical coupling. The experimental results show that the optical properties and structural morphology of TCPP‐(FF)4 supermolecular assemblies can be precisely controlled by adjusting the types of solvents and pH. Moreover, the TCPP‐(FF)4 can self‐assemble into nanohelix with photocatalytic activity, which can be used as a catalyst for enantioselective photocatalysis of tyrosine (Tyr) into di‐tyrosine (di‐Tyr), which provides a promising strategy for the development of enantioselective photocatalysts.
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