Chemostratigraphy of Neoproterozoic cap carbonates from the Volta Basin, West Africa

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The Neoproterozoic Era includes some of the most extreme ice ages in Earth history. The exact number of glaciations is unknown, although there were at least two events of global reach and possibly an equal number of lesser advances. Neoproterozoic glacial deposits in West Africa have proven particularly difficult to correlate with better constrained successions elsewhere. In most West African successions, only a single glaciogenic deposit is present, generally within a stratigraphic ‘Triad’of tillite, carbonate, and bedded chert; the age of these deposits and their synchroneity across the craton remain controversial. We report isotopic data from carbonates that cap tillites in the Volta Basin (Sud-Banboli Group). In the three sections measured, ∂13C (‰ PDB) begins at ∼−2 to −3 and drops to −5 to −8, correlated with a drop in both ∂18O and Mg/Ca. This pattern—both the drop in ∂13C and its correlation with ∂18O and lithology—has been observed in Neoproterozoic cap carbonates on other cratons, suggesting that it reflects primary depositional variations. In addition, the strong positive correlation among lithology, ∂13C, and ∂18O suggests that lithological variation may have exerted a principal control on isotopic variation, implying that the dolomite formed in isotopic equilibrium with seawater, as a primary precipitate or very early diagenetic replacement. This would require low levels of sulfate (estimated to be ∼1 mM or less), consistent with available S-isotopic data, the presence of barite crusts in association with some cap carbonates, and the conditions of seawater chemistry hypothesized in the aftermath of a ‘snowball Earth.’