Abstract
The use of palladium–NHC (bulky) catalyst enables selective acylative coupling in esters via blocking the potential C(aryl)–O oxidative addition and decarbonylation processes. Mechanistic studies elucidate the role of bulky carbene catalysts in promoting C(acyl)–O activation, and as a result, the acyl metal intermediates undergo coupling without the loss of carbonyl group.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
