Abstract

Etude RX des complexes [Pd(C 16 H 22 N 4 ) 2 ]Cl 2 •3H 2 O et [Pd(C 16 H 22 N 4 )]Cl 2 •3H 2 O ou C 16 H 22 N 4 =bis(methyl-6 pyridyl-2)-1,6 diaza-2,5 hexane: cristallisation dans P1 avec Z=2 dans les deux cas; affinement jusqu'a R=0,031 et 0,049 respectivement. Etude RX de [Pd(C 17 H 24 N 4 )] Cl 2 3H 2 O ou (C 17 H 24 N 4 =bis-(methyl-6 pyridyl-2)-1,7 diaza-2,6 heptane: cristallisation dans P1 avec Z=2; affinement jusqu'a R=0,029. Coordination plan carre comme prevu dans les trois cas

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