ChemInform Abstract: Synthesis and Suzuki—Miyaura Cross‐Coupling of Enantioenriched Secondary Potassium β‐Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β‐Unsaturated Carbonyl Compounds.

Abstract

AbstractEnantioenriched title compounds are synthesized via a new asymmetric, copper‐catalyzed addition of tetrahydroxydiboron to various α,β‐unsaturated amides, ketones, and esters in high yields and enantioselectivities.