Abstract
Rh-Catalyzed asymmetric 1,4-selective addition of arylboronic acids to beta,gamma-unsaturated alpha-keto ester was developed using chiral tert-butanesulfinylphosphine as ligand, good yields (up to 87%), good 1,4-regioselectivities (up to 96:4), and high enantioselectivities (up to 94% ee) were achieved. (C) 2014 Elsevier Ltd. All rights reserved.
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