Abstract

AbstractReaction of azide ion with the 2‐O‐trifluoromethanesulfonate derived from the D‐glycero‐D‐talo‐heptano‐1,5‐lactone (I) yields the D‐glycero‐D‐galacto lactone (IV), which isomerizes to the more stable D‐glycero‐D‐talo lactone (V).

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