ChemInform Abstract: Regiocontrolled Cyclization of Acetylenic Ketones. First Example of Selective Desilylation of a Triple Bond in the Presence of a Silyl Enol Ether.

J Drouin,M A Boaventura

doi:10.1002/chin.198805126

ChemInform Abstract: Regiocontrolled Cyclization of Acetylenic Ketones. First Example of Selective Desilylation of a Triple Bond in the Presence of a Silyl Enol Ether.

J Drouin, M A Boaventura

https://doi.org/10.1002/chin.198805126

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Journal: ChemInform

Publication Date: Feb 2, 1988

Affiliation: University of Paris-Sud, Institut Polytechnique de Paris, French National Centre for Scientific Research

#Octanone Derivatives #Tricyclic Ketones #Selective Desilylation #Silyl Enol Ether #Acetylenic Ketones #Triple Bond #Enol Ether

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AbstractCyclization of the 1‐(3‐butyryl)bicyclo(3.3.0)octanone derivatives (I), (Vb), or (VIII) yields the propellanes (II) or (IX) and/or the tricyclic ketones (III) or (VI).

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ChemInform Abstract: Regiocontrolled Cyclization of Acetylenic Ketones. First Example of Selective Desilylation of a Triple Bond in the Presence of a Silyl Enol Ether.