ChemInform Abstract: Reaction of Singlet Oxygen with Enolic Tautomers of β-Dicarbonyls. α-Hydroxylation of 2-Acyl- and 2-Carboalkoxy-3,4- dihydronaphthalen-1(2H)-ones.

M Yoshioka,T Nishioka,T Hasegawa

doi:10.1002/chin.199202184

ChemInform Abstract: Reaction of Singlet Oxygen with Enolic Tautomers of β-Dicarbonyls. α-Hydroxylation of 2-Acyl- and 2-Carboalkoxy-3,4- dihydronaphthalen-1(2H)-ones.

M Yoshioka, T Nishioka + Show 1 more

https://doi.org/10.1002/chin.199202184

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Journal: ChemInform

Publication Date: Aug 22, 2010

Affiliation: Saitama University

#Reaction Of Singlet Oxygen #Dye-sensitized Photooxidation #Enolic Tautomers #Singlet Oxygen

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Abstract Dye-sensitized photooxidation of enolic tautomers of naphthalenones (5) gave hydroperoxynaphthalenones (6) and naphthols (7). Deoxygenation of 6 by triphenylphosphine gave hydroxynaphthalenones (8).

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ChemInform Abstract: Reaction of Singlet Oxygen with Enolic Tautomers of β-Dicarbonyls. α-Hydroxylation of 2-Acyl- and 2-Carboalkoxy-3,4- dihydronaphthalen-1(2H)-ones.