Abstract

Abstract Radical polymerization and copolymerization reactions involving olefin substituted cyclophosphazenes lead to hybrid inorganic-organic polymers and copolymers, which are characterized by a carbon-carbon backbone and pendant phosphazenic groups. The stability of the polymers prepared is related to their structures. The thermal behaviour of poly(cyclophosphazenemethacrylate) (PCPhMA), which appears to possess flame-retardant properties, is compared with that of poly(methylmethacrylate) (PMMA).

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