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https://doi.org/10.1002/chin.201613029
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Cite Journal: ChemInform |  Publication Date: Mar 1, 2016 |
Affiliation: National University of Singapore
The first phosphine catalysed Michael addition of arylcyanoacetates to allenoates has been developed, and the β-selective products with a quaternary center were obtained in excellent yields. This unusual regioselectivity may open new opportunities to access interesting molecular structures.
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