Abstract
AbstractThe complex (μ2‐O2)PrO2 and the linear core‐containing PrO2+ complexes are observed both in the gas phase by laser vaporization of Pr in He2 seeded with a pulsed 30—40% O2 stream (1‐1.2 MPa) and in solid Ar matrices analyzed by matrix isolation IR and IR photodissociation spectroscopy (0.2—0.5 mJ/pulse, 850—1600 cm‐1) with TOF‐MS‐selected [(PrO2)+(O2)n] cations.
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