ChemInform Abstract: Oxidative‐Addition Reactions of Potassium Tetrachloroplatinate(II) with N,N‐Dialkylacetamides Under Mild Reaction Conditions. Synthesis of cyclic [cis‐Pt(CH2N(CH3)C(CH3)O)2‐trans‐Cl2] and [trans‐Pt(OC(CH3)N(CH3)2)2‐trans‐Cl2

R M Roat,S Yolles,A L Rheingold

doi:10.1002/chin.198652274

ChemInform Abstract: Oxidative‐Addition Reactions of Potassium Tetrachloroplatinate(II) with N,N‐Dialkylacetamides Under Mild Reaction Conditions. Synthesis of cyclic [cis‐Pt(CH2N(CH3)C(CH3)O)2‐trans‐Cl2] and [trans‐Pt(OC(CH3)N(CH3)2)2‐trans‐Cl2

R M Roat, S Yolles + Show 1 more

https://doi.org/10.1002/chin.198652274

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Journal: Chemischer Informationsdienst

Publication Date: Dec 30, 1986

#Title Complex #Potassium Tetrachloroplatinate + Show 1 more

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AbstractOn combining potassium tetrachloroplatinate(II) with N,N‐dimethylacetamide(DMA), at 60 ° C, an oxidative‐addition, ortho‐metalation reaction occurs and gives the Pt(IV) title complex (I) and small amount of the trans‐Pt(II) product (II).

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