ChemInform Abstract: Orthogonally Protected Schoellkopf′s Bis‐Lactim Ethers for the Asymmetric Synthesis of α‐Amino Acid Derivatives and Dipeptide Esters.

Marc Hutchby,Adam C Sedgwick,Steven D Bull

doi:10.1002/chin.201647207

ChemInform Abstract: Orthogonally Protected Schoellkopf′s Bis‐Lactim Ethers for the Asymmetric Synthesis of α‐Amino Acid Derivatives and Dipeptide Esters.

Marc Hutchby, Adam C Sedgwick + Show 1 more

https://doi.org/10.1002/chin.201647207

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Journal: ChemInform

Publication Date: Nov 1, 2016

Affiliation: University of Bath

#Dipeptide Ester #Alkyl Halides #Acid Derivatives #Acid Dipeptide #Ester Derivatives #Asymmetric Synthesis

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AbstractA diastereoselective trans‐alkylation of aza‐enolates of orthogonally protected chiral bis‐lactim ethers with electrophiles, such as alkyl halides, and subsequent deprotection via hydrolysis/hydrogenation leads to dipeptide ester derivatives.

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ChemInform Abstract: Orthogonally Protected Schoellkopf′s Bis‐Lactim Ethers for the Asymmetric Synthesis of α‐Amino Acid Derivatives and Dipeptide Esters.