ChemInform Abstract: New Family of Materials with Negative Coefficients of Thermal Expansion: The Effect of MgO, CoO, MnO, NiO, or CuO on the Phase Stability and Thermal Expansion of Solid Solution Phases Derived from BaZn2Si2O7.

Christian Thieme,Christian Ruessel,Stephan Heitmann,Tina Waurischk

doi:10.1002/chin.201628006

ChemInform Abstract: New Family of Materials with Negative Coefficients of Thermal Expansion: The Effect of MgO, CoO, MnO, NiO, or CuO on the Phase Stability and Thermal Expansion of Solid Solution Phases Derived from BaZn2Si2O7.

Christian Thieme, Christian Ruessel + Show 2 more

https://doi.org/10.1002/chin.201628006

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Journal: ChemInform

Publication Date: Jun 1, 2016

Affiliation: Schott (Germany)

#Negative Coefficients Of Thermal Expansion #Stability Of Solid Phases #Effect Of CoO #Phase Stability #Reactions Of Carbonates #Thermal Expansion #Metal Carbonates #Reactions Of Oxides #Intermediate Steps #Solid Phases

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AbstractReplacement of Zn in Sr0.5Ba0.5Zn2Si2O7 by Mg and Co (0.1—0.7), Mn (0.1—0.5), Ni (0.1—0.3), and Cu (0.1, 0.2) is performed by solid state reactions of metal oxides or carbonates (1100—1300 °C, 30—50 h) with intermediate grinding steps.

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ChemInform Abstract: New Family of Materials with Negative Coefficients of Thermal Expansion: The Effect of MgO, CoO, MnO, NiO, or CuO on the Phase Stability and Thermal Expansion of Solid Solution Phases Derived from BaZn2Si2O7.