ChemInform Abstract: Multicomponent Reactions of Phosphines, Diynedioates, and Aryl Aldehydes Generated Furans Appending Reactive Phosphorus Ylides Through Cumulated Trienoates as Key Intermediates: A Phosphine α‐Addition‐δ‐Evolvement of an Anion Pathway.

Jie‐Cheng Deng,Shih‐Ching Chuang

doi:10.1002/chin.201517250

ChemInform Abstract: Multicomponent Reactions of Phosphines, Diynedioates, and Aryl Aldehydes Generated Furans Appending Reactive Phosphorus Ylides Through Cumulated Trienoates as Key Intermediates: A Phosphine α‐Addition‐δ‐Evolvement of an Anion Pathway.

Jie‐Cheng Deng, Shih‐Ching Chuang

https://doi.org/10.1002/chin.201517250

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Journal: ChemInform

Publication Date: Apr 1, 2015

Affiliation: National Yang Ming Chiao Tung University

#Key Intermediates #Reactions Of Ylides #Addition Of Phosphines #Reactions Of Phosphines #Synthesis Of Furans #Anion Pathway #Aldehydes Generated #Phosphorus Ylides #Aryl Aldehydes #Reactive Phosphorus

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AbstractThe title synthesis of furans involves an initial novel α(δ′)‐addition of phosphines to diynedioates followed by addition reaction of the resulting trienoates to aldehydes and subsequent 5‐endo‐dig cyclization.

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ChemInform Abstract: Multicomponent Reactions of Phosphines, Diynedioates, and Aryl Aldehydes Generated Furans Appending Reactive Phosphorus Ylides Through Cumulated Trienoates as Key Intermediates: A Phosphine α‐Addition‐δ‐Evolvement of an Anion Pathway.