Abstract
The asymmetric hydrosilylation of acetophenone with Ph2SiH2 has been investigated in the presence of (S)-amphos as the chiral ligand in combination with the cyclooctadiene-rhodium(I), -iridium(I), -palladium(II), and -platinum(II) chloride complexes. High activity and optical yields up to 50% ee have been obtained. The product configuration induced by the rhodium system is (S), in all other cases it was (R).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
