Abstract

AbstractBy using variously tritiated hexoses [(6RS)‐D‐[1‐14C,6‐T]glucosamine,(6RS)‐D‐[6‐14C,6‐T]glucose, D‐[U‐14C,5‐T]glucose, D‐[U‐14C′3,4‐T2]glucose] and Streptomyces fradiae (a neomycin producer), the mechanism and stereochemistry of the formation of various subunits of neomycin B (I) are investigated.

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