ChemInform Abstract: Ligand‐Controlled Chemoselectivity in Potassium tert‐Amylate‐Promoted Direct C—H Arylation of Unactivated Benzene with Aryl Halides.

Wei Liu,Lige Xu

doi:10.1002/chin.201536108

ChemInform Abstract: Ligand‐Controlled Chemoselectivity in Potassium tert‐Amylate‐Promoted Direct C—H Arylation of Unactivated Benzene with Aryl Halides.

Wei Liu, Lige Xu

https://doi.org/10.1002/chin.201536108

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Journal: ChemInform

Publication Date: Aug 20, 2015

Affiliation: Henan University of Technology

#Arylation Of Benzene #Aryl Halides #Unactivated Benzene #Protocol For Preparation #Small Ligands

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AbstractPotassium tert‐amylate promotes the direct C—H arylation of benzene in the presence of small ligands like dimethylethylenediamine or phen, providing an efficient, transition‐metal‐free radical cross‐coupling protocol for preparation of biaryls.

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ChemInform Abstract: Ligand‐Controlled Chemoselectivity in Potassium tert‐Amylate‐Promoted Direct C—H Arylation of Unactivated Benzene with Aryl Halides.