ChemInform Abstract: Inverse Electron Demand Asymmetric Cycloadditions of Cyclic Carbonyl Ylides Catalyzed by Chiral Lewis Acids - Scope and Limitations of Diazo and Olefinic Substrates.

Hiroyuki Suga,Toshihide Baba,Akikazu Kakehi,Yuta Hashimoto,Satoshi Higuchi,Daisuke Ishimoto,Motoo Ohtsuka,Teruko Tsuchida,Shunta Misawa,Tadashi Arikawa

doi:10.1002/chin.201034100

ChemInform Abstract: Inverse Electron Demand Asymmetric Cycloadditions of Cyclic Carbonyl Ylides Catalyzed by Chiral Lewis Acids - Scope and Limitations of Diazo and Olefinic Substrates.

Hiroyuki Suga, Toshihide Baba + Show 8 more

https://doi.org/10.1002/chin.201034100

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Journal: ChemInform

Publication Date: Jul 29, 2010

Affiliation: Shinshu University

#Chiral Lewis Acids #Α-diazocarbonyl Compounds + Show 8 more

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Abstract

The reaction of activated olefins with carbonyl ylides, generated by Rh-catalyzed decomposition of the corresponding α-diazocarbonyl compounds, is investigated in the presence of transition metal triflates and Pybox or BINIM-type ligands as catalysts (to be continued).

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