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https://doi.org/10.1002/chin.200024053
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Cite Journal: ChemInform |  Publication Date: Jun 8, 2010 |
Affiliation: Technische Universität Berlin
Abstract Seven-membered ring annulation is achieved by an intramolecular Michael reaction catalyzed by iron(III) chloride hexahydrate. Reaction conditions are mild and non-basic, and chemo- and stereoselectivity is excellent. Contrastingly, this method fails for a 17-membered ring annulation.
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