Abstract
Abstract Interaction of Os3(CO)12 has been studied with SiO2 and La2O3. On SiO2, a hydridotriosmiumcarbonyl is formed at 50 middot; C. The cluster breaks up at 250 middot; C. On La2O3 the osmium cluster breaks up at room temperature forming mononuclear tri- and dicarbonyl osmium species. At 250 middot; C, only the dicarbonyl survives but the tricarbonyl can be regenerated by treatment with CO.
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