Abstract

AbstractThe asymmetric rhodium‐catalyzed addition reaction of potassium alkenyltrifluoroborates to acyclic aldimines provides a reliable and scalable method for the modular synthesis of chiral α‐branched allylic amines.The reactions with different combinations of imines and alkenyl trifluoroborates proceed smoothly affording high yields and excellent enantioselectivities.

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