Abstract
It was shown by cyclic voltammetry and electrolysis at controlled potential at a platinum electrode and also by TLC and UV spectroscopy that the electrochemical oxidation of substituted 1H-1,2-diazaphenalenes in anhydrous acetonitrile takes place in a single one-electron stage with the formation of a stable radicalation. The oxidation potentials of a series of derivatives of 1H-1,2-diazaphenalene and the parameters of the equation for the correlation of these potentials with the Taft substituent constants were determined.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have