Abstract
Abstract Enolate anions derived from 2-substituted 2-acyl-1,3-dithiane 1-oxides react readily with the nitrogen electrophile di- tert -butyl azodicarboxylate (DBAD) to give α-aminoketones with good diastereoselectivity and in reasonable yields; in some cases diastereoselectivity appears sufficiently high that the minor isomer cannot be detected by 400 MHz 1 H NMR spectroscopy.
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