ChemInform Abstract: Copper Mediated Defluorinative Allylic Alkylation of Difluorohomoallyl Alcohol Derivatives Directed to an Efficient Synthetic Method for (Z)‐Fluoroalkene Dipeptide Isosteres.

Daisuke Watanbe,Yuko Nakamura,Midori Okada,Takeo Taguchi,Hikaru Yanai,Akio Saito,Minoru Koura,Azusa Sato

doi:10.1002/chin.201139188

ChemInform Abstract: Copper Mediated Defluorinative Allylic Alkylation of Difluorohomoallyl Alcohol Derivatives Directed to an Efficient Synthetic Method for (Z)‐Fluoroalkene Dipeptide Isosteres.

Daisuke Watanbe, Yuko Nakamura + Show 6 more

https://doi.org/10.1002/chin.201139188

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Journal: ChemInform

Publication Date: Sep 1, 2011

Affiliation: Tokyo University of Pharmacy and Life Sciences

#Fluoroalkene Dipeptide Isosteres #Fluoroalkene Dipeptide #Efficient Method #Efficient Synthetic Method #Dipeptide Isosteres #Allylic Alkylation #Alcohol Derivatives #Synthetic Method

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AbstractCopper‐mediated defluorinative allylic alkylation of difluorohomoallyl alcohol derivatives of type (III) or (IV) is used as key step for the synthesis of (Z)‐fluoroalkene dipeptide isosters, e.g. (XI).

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ChemInform Abstract: Copper Mediated Defluorinative Allylic Alkylation of Difluorohomoallyl Alcohol Derivatives Directed to an Efficient Synthetic Method for (Z)‐Fluoroalkene Dipeptide Isosteres.