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https://doi.org/10.1002/chin.201632215
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Cite Journal: ChemInform |  Publication Date: Jul 1, 2016 |
Affiliation: The University of Texas Southwestern Medical Center
Axinellamines A and B are broad-spectrum antibacterial pyrrole–imidazole alkaloids that have a complex polycyclic skeleton. A new asymmetric synthesis of these marine sponge metabolites is described herein, featuring an oxidative rearrangement and an anchimeric chlorination reaction.
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