ChemInform Abstract: Asymmetric Syntheses via Heterocyclic Intermediates. Part 40. Acylation of Lithiated Bislactim Ethers of cyclo(‐L‐Val‐Ala‐) and cyclo(‐L‐Val‐Gly‐). Asymmetric Synthesis of (R)‐α‐Alkenyl and (R)‐α‐Ethinyl Alanine Methyl Esters by the Bislactim Ether Method.

U + Schoellkopf, K Horn + Show 2 more

https://doi.org/10.1002/chin.198849102

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Publication Date: Dec 6, 1988

Abstract

AbstractThe lithiated bislactim ether (III) from (I) reacts with acyl chlorides (II) highly diastereoselectively to yield the ketones (IV).

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