Abstract
Abstract Treatment of chiral crystals of 2,3:5,6-dibenzobicyclo[2.2.2]octa-2,5,7-triene (dibenzobarrelene, 1) with bromine vapor results in the formation of the rearranged product syn -8-bromo- endo -4-bromo2,3:6,7-dibenzobicyclo[3.2.1]octa-2,6-diene (2) in up to 8% enantiomeric excess.
Published Version
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