Abstract
AbstractPolymers of ethylene methacrylate, toluene‐, and benzenesulfonate are shown to be strongalkylating agents. Their polymer‐analogous reaction with most nucleophiles proceeds smoothly under conditions comparable to those of low molecular analogs. The nucleophiles used successfully were of the nitrogen type: amines, pyridine, phthalimidate, azide; or oxygen: alkoxide, phenolate, carboxylate; sulfur: thioacetate, thiocyanate, thiourea; and other types: iodide. Further reaction of some of these derivatives, e.g., hydrolysis to thiol or amine, proceeds as expected.
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