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Abstract
Modification of single-walled carbon nanotube (SWNT) channels by intercalation of semiconductor crystals leads to a change of the electronic structure of nanotubes, as was observed by Raman spectroscopy of CdI2@SWNT and CdS@SWNT composites (see the Supporting Information for details). The composites exhibit the upward shift of RBM and G vibrational frequencies as compared to raw SWNTs, which is attributed to depletion of electrons from the SWNT walls to the intercalated compound
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