Chemical order around Ge atoms in binary germanium selenide glasses: Results from 73Ge solid-state NMR spectroscopy at 19.6 Tesla

Abstract

The coordination environment of Ge atoms in binary Ge x Se 100- x glasses with 75 ≥ x ≥ 60 is probed using 73Ge solid-state NMR spectroscopy at an ultra-high magnetic field of 19.6 T. Two different types of Ge coordination environments can be identified in the 73Ge NMR spectra of glasses with x ≥ 66.7, one is a relatively symmetric GeSe 4 tetrahedral site with all heteropolar Ge–Se bonds and the other is a distorted GeSe 4- n Ge n tetrahedral site with one or more Ge–Ge homopolar bonds. The compositional variation of the relative fractions of these two types of Ge sites provides unique information regarding degree of chemical order and nature of the spatial distribution of Ge–Ge bonds in these glasses. These results also demonstrate the potential of 73Ge solid-state NMR as an important technique for future structural studies of Ge containing crystalline and amorphous materials.