Abstract
Chemical shifts and full widths at half maximum intensity (FWHM) of Kα and Kβ1,3 X-ray emission lines were measured for the following Fe compounds: Fe, FeCl2, FeCl3·6H2O, FeF2, FeF2·4H2O, FeF3, FeF3·3H2O, FeO3, FeS2, FeSO4. The measurements were performed with a wavelength-dispersive X-ray fluorescence spectrometry (WDXRF). It was found that the calculated results for Fe compounds are strongly correlated with the oxidation state. At the same time chemical effects for halogens compounds are generally more than that other compounds.
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