Charge heteroaggregation between hard and soft particles.

Abstract

In this paper, the heteroaggregation of opposite sign hard and soft colloidal particles has been studied by static and dynamic light scattering. The structure of the aggregates, as well as the aggregation kinetics, have been investigated. At low electrolyte concentration, where both long-range electrostatic repulsive and attractive forces are present, the aggregates were found to be more open than expected for diffusion-limited cluster aggregation (DLCA). However, the aggregate size time evolution is characteristic of diffusion-controlled processes. At high electrolyte concentration, where DLCA would be expected, very compacted clusters were found, as well as very rapid aggregation, leading to high polydispersity. These latter findings are interpreted in terms of the differences in the homoaggregation speeds for the hard and soft particles.