Characterizations and mechanisms for synthesis of chitosan-coated Na-X zeolite from fly ash and As(V) adsorption study.

Abstract

Solid waste fly ash with low aluminum of Yunnan Province in China was used as pristine material to prepared chitosan-coated Na-X zeolite, and the obtained composite material was employed as As(V) adsorbent. Then, the prepared materials were characterized by XRD, FT-IR, and XPS. And the results suggested that the low aluminum fly ash was successfully convert into Na-X zeolite, and the mineralization between Si-OH of the obtained Na-X zeolite and C-OH of chitosan was the dominated mechanism for coated chitosan over the surface of Na-X zeolite. From the batch experiments of As(V) removal, it has been found that the coated chitosan could significantly improve As(V) performance of Na-X zeolite. The optimal working pH for removal As(V) by chitosan-coated Na-X zeolite was attained at pH2.1 ± 0.1, and the maximum adsorption capacity was 63.23mg/g. And the adsorption data at different interval time was excellent fitted by pseudo-second-order kinetic model. From the analyze of XPS, the results suggested that As(V) uptake over adsorbent by the bond of As-N and As-O and the surface hydroxyl group of Al-OH and -NH2 were involved in uptake As(V) from acid wastewater.