Characterization of Y/MCM-41 composite molecular sieve with high stability from Kaolin and its catalytic property

Abstract

A novel Y/MCM-41 composite material with high stability was developed based on pretreated kaolin. The obtained samples are characterized with the help of several modern techniques such as XRD, SEM, TEM, NH3–TPD and N2 physical adsorption. The effect of various factors, such as crystallization temperature and crystallization time on the structure formation of the sample was investigated in detail. The thermal and hydrothermal stabilities of the sample were evaluated and its catalytic activity in alkylation of phenol with tert‐butyl alcohol was also tested. The results show the presence of mesoporous MCM-41 and microporous Y type molecular sieves in the composite. The resulting composite has the specific surface area of 550.4m2/g and the average pore size is ca. 2.74nm. The thermal and hydrothermal treatment results show that the mesoporous framework still retains even after calcining at 800°C for 3h or hydrothermally treatment at 100°C for 10days. Under optimum catalytic condition of the molar ratio of tert‐butyl alcohol to phenol is 2.0, weight hour space velocity (WHSV) is 1.0, the reaction time is 1h, the reaction temperature is 140°C, the conversion of phenol and the selectivity to 4‐tert‐butyl‐phenol are 62.3% and 86.2%, respectively.