Abstract
This research reports upon the chemical constituent of the aerial part of <em>Bacopa caroliniana</em> identified using the liquid chromatography with electrospray ionization/mass spectrometry (LC-ESI-QTOF-MS/MS) technique. The LC separation along with high resolution mass spectrometry data revealed significant differences in phytochemicals of <em>B. caroliniana</em>. The mass spectral fragmentation patterns in both positive and negative modes indicated the numbers, positions, and linkages of sugar moieties in the saponin structures.
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