Abstract
In this work, a method to characterize reliably the porosity and pore size distribution of ultra-thick LiNi0.6Co0.2Mn0.2O2 (NCM622) electrodes with mercury intrusion porosimetry is presented. In terms of sample preparation, a large sample area and low sample mass are essential to prevent inter-sample voids during analysis. The sample mass must be high enough to achieve a low relative error in terms of intrusion volume. Moreover, it was demonstrated that during analysis the protective oxide layer of the aluminum foil appears to be breached due to the high applied pressure and Al⋅Hg alloy is formed. The influence of this effect on the mercury intrusion porosimetry results was analyzed by investigations with blank aluminum foil. Thick electrodes with pore size distributions varied by the overall density, mechanical perforation and preparation with a pore forming agent were analyzed with the developed method and the results obtained for the very different structures are discussed.
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