Characterization of N-isopropyl acrylamide/acrylic acid grafted polypropylene nonwoven fabric developed by radiation-induced graft polymerization

Abstract

Radiation-induced graft copolymerization of N-isopropylacrylamide (NIPAAm) and acrylic acid (AA) mixture was carried out on polypropylene nonwoven fabric to develop a thermosensitive material and has been found to affect the thermal and physical characteristics of fabric. The grafted fabrics with different monomer ratios were characterized by thermal gravimetric analysis (TGA), fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), X-ray diffraction (XRD), contact angle and atomic force microscopy (AFM). Results of FTIR clearly indicated that poly(acrylic acid) and poly(N-isopropyl acrylamide) were successfully grafted onto the membrane surface. TGA results showed that the thermal stability of PP fabric increased after grafting of NIPAAm/AA. The crystallinity values from DSC and XRD were found to decrease with increase in degree of grafting because of the addition of grafted chains within the noncrystalline region. The decrease in contact angles of the grafted fabric with an increase of the degree of grafting shows that PNIPAAm/PAA exists as the hydrophilic component. The increase in surface roughness after grafting was observed by AFM.