Characterization and Electrocatalytic Performance of Molasses Derived Co-Doped (P, N) and Tri-Doped (Si, P, N) Carbon for the ORR

Abstract

There is a growing need to develop sustainable electrocatalysts to facilitate the reduction of molecular oxygen that occurs at the cathode in fuel cells, due to the excessive cost and limited availability of precious metal-based catalysts. This study reports the synthesis and characterization of phosphorus and nitrogen co-doped carbon (PNDC) and silicon, phosphorus, and nitrogen tri-doped carbon (SiPNDC) electrocatalysts derived from molasses. This robust microwave-assisted synthesis approach is used to develop a low cost and environmentally friendly carbon with high surface area for application in fuel cells. Co-doped PNDC as well as tri-doped SiPNDC showed Brunauer–Emmet–Teller (BET) surface areas of 437 and 426 m2 g−1, respectively, with well-developed porosity. However, examination of X-ray photoelectron spectroscopy (XPS) data revealed significant alteration in the doping elemental composition among both samples. The results obtained using rotating disk electrode (RDE) measurements show that tri-doped SiPNDC achieves much closer to a 4-electron process than co-doped PNDC. Detailed analysis of experimental results acquired from rotating ring disk electrode (RRDE) studies indicates that there is a negligible amount of peroxide formation during ORR, further confirming the direct-electron transfer pathway results obtained from RDE. Furthermore, SiPNDC shows stable oxygen reduction reaction (ORR) performance over 2500 cycles, making this material a promising electrocatalyst for fuel cell applications.