Characteristics of dissolved organic matter in two alternative water sources: A comparative study between reclaimed water and stormwater

Abstract

Reclaimed water and stormwater are two important alternative water sources to mitigate water resource shortage. They can be reused by discharging into drinking water sources. Due to different sources, characteristics of dissolved organic matter (DOM, a precursor of disinfection by-products, DBPs) present in reclaimed water and stormwater would be different. This study selected reclaimed water to compare with stormwater (including both stormwater runoff and rainwater) by investigating their DOM characteristics, including concentrations, aromaticity, molecular weight, hydrophobicity/hydrophilicity, composition and DBPs formation potential. The results showed that reclaimed water had higher dissolved organic carbon (DOC) concentrations (6.02–10.8 mg/L) than stormwater (3.62–5.48 mg/L) while SUVA254 values of stormwater runoff (1.92–2.53 L/(mg-C·m)) were higher than reclaimed water (1.11–1.24 L/(mg-C·m)). Additionally, reclaimed water is more hydrophobic while stormwater runoff and rainwater are more hydrophilic. Although all water types included the highest fraction of DOM with molecular weight <1 kDa (43.0 %–77.5 %), reclaimed water primarily contained soluble microbial products (SMPs)-like and humic acid-like substances while stormwater runoff primarily contained humic acid-like DOM. In terms of DBPs, reclaimed water showed relatively higher formation potential than stormwater runoff while rainwater had the lowest DBPs formation potential. These results can contribute to effective water resource management. Particularly, when reclaimed water or/and stormwater are discharged into drinking water sources, these outcomes can help on efficient drinking water treatment.