Characteristic Temperatures of the Mössbauer Fraction and Thermal-Shift Measurements in Iron and Iron Salts

Abstract

Measurement of Mossbauer spectra in metallic iron, sodium nitroprusside, sodium ferrocyanide, and potassium ferrocyanide absorbers between 78 and 293 K. The temperature dependences of the Mossbauer fraction and the resonant velocity were fitted to Einstein and Debye lattice-vibration models. The characteristic temperatures of the models fitted to the Mossbauer fraction are consistently lower than those fitted to the resonant velocity showing the sensitivity of the Mossbauer fraction to low-frequency modes of vibration. The characteristic temperatures obtained from the resonant velocity are higher for the salts than for the metal, indicating the presence of higher-frequency modes in the salts. This interpretation is verified semiquantitatively by comparing the thermal-shift Debye temperatures of the salts to their infrared absorption frequencies. The Mossbauer fraction of potassium ferrocyanide shows a weaker temperature dependence than that expected for a harmonic solid, which suggests that potassium ferrocyanide is anharmonic in the temperature range studied.