Abstract

Abstract The theory underlying the adsorption behavior of carbons is discussed as a basis for quantitative analysis of their adsorption properties and microporous structure. The equations of the theory of volume filling of micropores for homogeneous and nonhomogeneous microporous structures and a rational method for determining the specific surface area of micropores are considered. Four principal parameters are proposed which describe the physical vapor adsorption with good accuracy and quantitatively characterize the microporous structure of carbonaceous adsorbents.

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