Abstract
Preparations of various types of chelating sulfonates preligands are reported. They include achiral and optically active phosphinosulfonate and imidazolium sulfonate zwitterionic species. Their coordination to transition metals forming the corresponding chelate complexes with palladium, nickel, platinum, rhodium, iridium, and ruthenium is described. Applications of the well-defined complexes of palladium, ruthenium, iridium, and rhodium, as well as in situ -generated copper derivatives in homogeneous catalysis for fine chemistry and polymerization complete this chapter.
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