Abstract

Photoelectrochemical CO2 reduction is a promising approach for promoting the sustainability of global development and solving environmental problems. In recent years, photoelectrochemical CO2 reduction has encountered a bottleneck and left the research hotspot, but there are still some meaningful and valuable works emerging. In this chapter, we analyze the state-of-the-art in the implementation of electrode structures and systems for photoelectrochemical CO2 reduction. We explore the mechanisms involved in active sites and the electron transfer of CO2 reduction to further optimize the activity, efficiency, and selectivity of photoelectrochemical CO2 reduction.

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