Abstract
As a combination of high-performance liquid chromatography (HPLC) and capillary electrophoresis (CE), the microfluidic and hybrid separation technique, namely, capillary electrochromatography (CEC) has attracted much attention of worldwide analytical scientists. CEC has the advantages of high efficiency, high resolution, high selectivity, with rapid analysis speed as well as low sample and solvent consumption. Because of the emerging reliable and dedicated instruments with sensitive and universal detector, thermostats with cooling capacity, efficient capillary columns, automatic samplers, pressurized CEC (pCEC) shows great potential in the applications in a variety of fields, such as biological, pharmaceutical, and environmental analyses. The feasibility of using extremely small particles (e.g., submicron particles) in CEC or pCEC column provides an opportunity to break through the existing bottleneck associated with column backpressure in ultraperformance liquid chromatography (UHPLC). CEC may eventually become a very effective and efficient separation technology.
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